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The older a sample is, the less (the period of time after which half of a given sample will have decayed) is about 5,730 years, the oldest dates that can be reliably measured by this process date to around 50,000 years ago, although special preparation methods occasionally permit accurate analysis of older samples.The idea behind radiocarbon dating is straightforward, but years of work were required to develop the technique to the point where accurate dates could be obtained.

The method was developed by Willard Libby in the late 1940s and soon became a standard tool for archaeologists.

Libby received the Nobel Prize in Chemistry for his work in 1960.

the average or expected time a given atom will survive before undergoing radioactive decay. The calculations involve several steps and include an intermediate value called the "radiocarbon age", which is the age in "radiocarbon years" of the sample: an age quoted in radiocarbon years means that no calibration curve has been used − the calculations for radiocarbon years assume that the , which for more than a decade after Libby's initial work was thought to be 5,568 years.

This was revised in the early 1960s to 5,730 years, which meant that many calculated dates in papers published prior to this were incorrect (the error in the half-life is about 3%).

By contrast, methane created from petroleum showed no radiocarbon activity because of its age.

The results were summarized in a paper in Science in 1947, in which the authors commented that their results implied it would be possible to date materials containing carbon of organic origin.

Libby and James Arnold proceeded to test the radiocarbon dating theory by analyzing samples with known ages.

For example, two samples taken from the tombs of two Egyptian kings, Zoser and Sneferu, independently dated to 2625 BC plus or minus 75 years, were dated by radiocarbon measurement to an average of 2800 BC plus or minus 250 years. Carbon dioxide produced in this way diffuses in the atmosphere, is dissolved in the ocean, and is taken up by plants via photosynthesis.

Atmospheric nuclear weapon tests almost doubled the concentration of concentrations in the neighbourhood of large cities are lower than the atmospheric average.


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